PA6/PA11-b-PPG热塑性弹性体的合成及性能表征
DOI:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:


Synthesis and Characterization of Polyamide Thermoplastic Elastomer Based on PA6/PA11-b-PPG
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    以聚丙二醇为软段,以尼龙6(PA6)与尼龙11(PA11)为硬段,合成了一系列尼龙6/尼龙11-b-聚丙二醇(PA6/PA11-b-PPG)型热塑性聚酰胺性体(简称TPAE)。通过核磁分析与红外光谱测试表征了其化学结构,采用差示扫描量热法以及热重分析考察了TPAE的热性能。并测试了其动态热机械性能与力学性能。表征结果表明:1)合成的TPAE具有良好的热稳定性能;2)随着嵌段共聚物中尼龙11质量分数的增加,其玻璃化转变温度(Tg)逐渐降低;3)随着尼龙11质量分数的增加,TPAE的拉伸强度、弯曲强度逐渐降低,而冲击强度和断裂伸长率逐渐升高。

    Abstract:

    Studied the synthesis of a series of nylon 6/ nylon 11 b polypropylene glycol (PA6/PA11-b-PPG) thermoplastic polyamide elastomer (TPAE) with polypropylene glycol as the soft segment and nylon 6 and nylon 11 (PA6) (PA11) as the hard segment. The chemical structure was characterized by NMR and IR spectra; The thermal performance of TPAE was investigated by differential scanning calorimetry and thermogravimetric analysis; the dynamic thermal mechanical properties and mechanical properties were tested. The results showed that: 1) the synthesis of TPAE has good thermal stability; 2) with the increase of mass fraction of nylon 11 block copolymers, the glass transition temperature (Tg) decreased gradually; 3)with the increase of nylon 11 content, the tensile strength bend strength of TPAE, gradually reduced, while the impact strength and break elongation increased gradually.

    参考文献
    相似文献
    引证文献
引用本文

张黄平,黄安民,王文志,曹凯凯,彭 军. PA6/PA11-b-PPG热塑性弹性体的合成及性能表征[J].湖南工业大学学报,2016,30(2):72-76.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2016-01-27
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2016-05-30
  • 出版日期:
文章二维码