老化对风电叶片用环氧树脂性能的影响
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Effects of Aging on Properties of Epoxy Resin for Wind Turbin Blade
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    摘要:

    采用差式扫描量热法、红外光谱分析法、静态力学分析法测试了树脂浇注体老化前后的玻璃化转变温度Tg和力学强度参数,并对环氧树脂浇注体的老化机理进行了分析。结果表明:经240 h湿热和盐雾老化后力学强度参数值和Tg都下降了,而经240 h冷热循环老化后力学强度参数值和Tg均有所提高。老化机理分析表明:湿热和盐雾老化后,树脂浇铸体由于水分子的浸入,产生了增塑效果,导致力学性能和Tg下降;而冷热老化后,树脂发生后固化反应,分子链交联密度进一步增大,因此,力学性能和Tg均提高。

    Abstract:

    By means of DSC, FITR and static mechanic tests, determined the glass transition temperature Tg and mechanical properties of epoxy resin castings before and after aging. The results showed that the mechanical properties and Tg decreased after 240 h hydrothermal aging and salt-spray test, while after 240 h thermal circulation aging, the mechanical properties and Tg increased. The aging mechanism analysis showed that after hydrothermal aging and salt-spray aging, Tg and mechanical properties decreased owing to the plasticization caused by water molecules immersion, while after thermal circulation aging, the Tg and mechanical properties increased because of cross-linking density caused by post-curing.

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卢 敏,唐先贺.老化对风电叶片用环氧树脂性能的影响[J].湖南工业大学学报,2011,25(4):33-36.

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  • 收稿日期:2011-04-08
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  • 在线发布日期: 2015-09-02
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