In view of three levels of higher, middle and primary on vocational education, the effects of these different levels of vocational education on the urbanization in the two aspects of the total and structure are analyzed. According to empirical analysis of the panel data from 1992 to 2013 in 30 provinces (excluding Tibet), it showed results that the Chinese vocational education can promote the development of urbanization，and the influence of different education levels on the urbanization is different. Higher vocational education has the greatest impact on urbanization in the Middle East，while the secondary vocational education has the biggest influence on the urbanization of the West. The primary vocational education has the inhibitory effect on the whole country and the region's urbanization, but the empirical result is not strong. Finally, it puts forward the policy suggestions by strengthening the information of the vocational education and the training of new citizens to strengthen the urbanization.