储存温度与时间对SiO2/芥酸酰胺复合改性LLDPE薄膜爽滑开口性能的影响
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TB333.2+3

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Effects of Storage Temperature and Time on the Slick Anti-Blocking Property of SiO2/Oleamide Composite Modified LLDPE Films
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    摘要:

    针对线型低密度聚乙烯(LLDPE)薄膜在实际应用中因高温或长期储存导致爽滑开口性能下降的问题,通过双螺杆挤出机制备LLDPE/芥酸酰胺和LLDPE/SiO2/芥酸酰胺母粒,使用吹膜工艺制备含有不同比例LLDPE的LLDPE/SiO2/芥酸酰胺薄膜,并进一步考察了不同储存时间及温度条件对薄膜爽滑开口性能和光学性能的影响。研究表明,芥酸酰胺可显著降低LLDPE薄膜的静摩擦系数(μs)和动摩擦系数(μk),SiO2与芥酸酰胺的协同效应则能有效解决单一爽滑剂在高温或长期储存下开口性能衰减的问题。当SiO2含量为0.199%时,薄膜在-10, 25, 50 ℃下均表现出优异的爽滑性能,且开口性能稳定可靠。SiO2均匀分散在LLDPE/SiO2/芥酸酰胺母粒和薄膜中,并作为LLDPE薄膜的成核剂,实现了LLDPE薄膜开口爽滑性能的长期稳定调控。

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    In response to the degradation of slip and anti-blocking properties in linear low-density polyethylene (LLDPE) films under high-temperature or long-term storage conditions, LLDPE/erucamide and LLDPE/SiO2/erucamide masterbatches were prepared via twin-screw extrusion. Films with varying proportions of SiO2 and erucamide were produced using the blown film process. The effects of different storage temperatures and durations on the slip/anti-blocking performance and optical properties of the films were systematically investigated. The results demonstrate that erucamide alone significantly reduces the static (μs) and kinetic friction coefficients (μk) of LLDPE films. Moreover, the SiO2-erucamide composite system exhibits a notable synergistic effect, effectively mitigating the decline in anti-blocking performance under extreme temperature or prolonged storage conditions. When the SiO2 content is 0.199%, the films exhibit excellent slip performance and reliable anti-blocking property across a broad temperature range (-10, 25, 50 ℃). The SiO2 particles are uniformly dispersed in both the masterbatch and the resulting films, serving as nucleating agents for LLDPE and contributing to the long-term stability of the slip and anti-blocking performance.

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邓祖豪,夏 霜,石 璞,王芳可,缪星星.储存温度与时间对SiO2/芥酸酰胺复合改性LLDPE薄膜爽滑开口性能的影响[J].包装学报,2026,18(2):26-32. 10.20269/j. cnki.1674-7100.2026.2004.

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  • 在线发布日期: 2026-02-09
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