导电水凝胶中交联剂含量对综合性能的影响
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湖南省自然科学基金资助项目(2020JJ4266);湖南省教育厅科学研究基金资助优秀青年项目(21B0530)


Effects of Cross-Linker Content on Microstructure and Mechanical Properties of Conductive Hydrogels
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    摘要:

    以丙烯酰胺(AM)为基体原料,N, N’-亚甲基双丙烯酰胺(MBAA)为交联剂,氯化钠(NaCl)为导电填料,采用自由基聚合的方法制备了聚丙烯酰胺(PAM)导电水凝胶,详细探究了交联剂含量对导电水凝胶力学行为和电学行为的影响。分别采用拉伸试验机和电化学工作站等手段对PAM导电水凝胶的力学性能及其导电行为进行了研究。结果表明:随着MBAA含量的增加,导致凝胶断裂伸长率及电导率下降,但回复性能提高。当将其组装成柔性传感器时,制备的导电水凝胶表现出了良好的传感性能(GF=1.76,ε=100%),并能够有效监测人体手指和膝盖的运动,表明导电水凝胶在人体健康监测领域具有良好的应用前景。

    Abstract:

    PAM conductive hydrogels were prepared by free radical polymerization using acrylamide (AM) as the main material, MBAA as cross-linker and NaCl as conductive component. The effects of crosslinker content on mechanical and conductivity properties of the hydrogel network were investigated in detail. The mechanical properties and electrical conductivity were studied by universal tensile machine, and electrochemical workstation respectively. It was found that with the increase of MBAA, the elongation at break and conductivity of the hydrogels was decreased as a result, while recovery performance was improved. When being assembled as flexible sensors, the prepared hydrogel displayed good sensing capacity with a gauge factor of 1.76 at a strain of 100%. Furthermore, the sensors were able to successfully detect the human motions such as finger bending and knee movements, which demonstrates that the conductive hydrogel holds great potential in human healthcare applications.

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邹 健,陈 卓,王盛冀,金 涛,易添灏,杨晓宇,经 鑫.导电水凝胶中交联剂含量对综合性能的影响[J].包装学报,2022,14(6):80-89.

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  • 收稿日期:2022-09-11
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  • 在线发布日期: 2023-05-12
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