According to the characteristics of pesticide packaging waste with small utilization value and accrued environmental impacts, combined with the incentive system of government subsidy, the changes of profit and recovery rate of the recovery system under government subsidy were analyzed by taking pesticide producers, pesticide retailers and third party recyclers respectively as the recycling principals based on the Stackelberg game analysis of behaviors among recycling principals. The results showed that the retailer recycling was the best rural pesticide packaging waste recovery model with the optimal profit and the maximum recovery rate to achieve the win-win economic and environmental benefits.