Ni2CoS4/还原氧化石墨烯/多孔还原氧化石墨烯的制备及其在超级电容器中的应用
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国家自然科学基金资助项目(21601057),湖南省自然科学基金资助项目(2019JJ40069)


College of Metallurgy and Material Engineering,Hunan University of Technology
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    摘要:

    采用水热法制备Ni2CoS4活性材料,通过物理过程和水热反应将其与氧化石墨烯(GO)、水热多 孔氧化石墨烯(HHGO)复合得到Ni2CoS4/还原氧化石墨烯/多孔还原氧化石墨烯(Ni2CoS4/RGO/HRGO)复 合电极材料。采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、循环伏安测试、恒流充放电测试和交 流阻抗测试等,对复合材料的形貌结构、电化学性能进行了表征。研究结果表明:在1 A/g的电流密度下 ,其比电容为1 684 F/g,在5 A/g的电流密度下循环2 000次后,其比电容保持率为91.8%。 Ni2CoS4/RGO/HRGO优良的电化学行为归因于这种复合结构使电解液对电极材料的润湿程度提高,进而提 高了离子和电荷的传输速率,同时也缓解石墨烯、Ni2CoS4的团聚和循环过程中的体积变化。因此, Ni2CoS4/RGO/HRGO是一种有良好应用前景的高性能超级电容器电极材料。

    Abstract:

    The Ni2CoS4 was prepared by hydrothermal method and further integrated with reduced graphene oxide (GO) and hydrothermal holey graphene oxide (HHGO) by a facile physical approach and hydrothermal reaction to obtain Ni2CoS4/RGO/HRGO composite electrode material. The morphology and structure as well as electrochemical properties of the prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy tests. The results showed that the specific capacitance of supercapacitor cathode material was 1 684 F/g at 1 A/g, and remained 91.8% after 2 000 cycles at 5 A/g. The superior electrochemical behavior of Ni2CoS4/RGO/HRGO could be attributed to the improved wettability of the electrolyte to the electrode material and the increased ion and charge transport rate. At the same time, the agglomeration of graphene and Ni2CoS4 and the volume change in the cycling process were alleviated as well. Therefore, Ni2CoS4/RGO/HRGO is a promising electrode material with application prospect for high performance supercapacitors.

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刘纪雷,朱裔荣,易文洁,袁文芳,陈宪宏. Ni2CoS4/还原氧化石墨烯/多孔还原氧化石墨烯的制备及其在超级电容器中的应用[J].包装学报,2019,11(5):1-8.

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  • 收稿日期:2019-08-18
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  • 在线发布日期: 2019-12-23
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