基于石墨烯的导电油墨配方优化设计
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湖南省自然科学基金资助项目(2016JJ6034),湖南省产业化培育基金资助 项目(15CY003)


Optimized Formulation Design of Graphene-Based Condnctive Ink
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    摘要:

    分析了不同原材料配比的石墨烯导电油墨性能。将石墨烯添加质量分数为26%, 28%, 30%, 32%的导电油墨分别编号为A、B、C、D,测量4组样品的电阻率、油墨细度, 分析印品的印刷质量。测试结果表明:随着石墨烯填充量的增加,导电油墨的电阻率逐 渐降低,导电油墨D的电阻率最小,为5.42 Ω cm;随着石墨烯含量的增加,油墨细度 随之增大,其值都在丝网印刷油墨适性细度范围之内;导电油墨D印刷的样品质量相对 最好。可得最佳的导电油墨配比为:连结料丙烯酸树脂、无水乙醇、丙三醇、苯甲酸、 导电碳粉、聚乙烯蜡、导电填料石墨烯的添加质量分数分别为18%, 34%, 11%, 2%, 2%, 1%, 32%。导电油墨D的导电性能较好,丝网印刷的样品质量也较高。

    Abstract:

    Graphene-based conductive ink of different proportions was analyzed with the research on its application. The conductive inks with mass fraction of added graphene of 26 %, 28 %, 30 % and 32 % were labeled as sample A, B, C, and D respectively. The electrical resistivity and ink fineness of four groups of samples were measured in order to analyze the printing quality. The result indicated that: firstly, the resistivity of the conductive ink gradually decreased with the increasing amount of graphene, while sample D reached the lowest of 5.42 Ω cm. Secondly,the ink fineness increased gradually with the increasing amount of graphene in the range of the ink fineness of silk-screen printing. Thirdly, the conductive ink of the sample D performed the best in printing quality. The optimal ratio of conductive inks could be with 18% of linking acrylic resin, 34% of ethanol, 11% of glycerol, 2% of benzoate, 2% of conductive toner, 1% of PE-wax, 32% of conductive material graphene. Sample D conductive ink with good electrical conductivity realized high printing quality.

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卢小伟,梁祐慈,钟云飞,陈 晗.基于石墨烯的导电油墨配方优化设计[J].包装学报,2017,9(3):89-94.

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  • 收稿日期:2017-01-03
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  • 在线发布日期: 2017-09-03
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