改性纳米SiO2填充PLA/PBAT复合体系的 结晶动力学研究
DOI:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

国家自然科学基金资助项目(11372108),湖南省自然科学基金资助项目(14JJ5021),厦门理工学院高层次人才基金资助项目(YKG14035R)


Crystallization Kinetics Research on PLA/PBAT Composites System Filled with Modified Nano-SiO2
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    利用Avrami方程,研究PLA及PLA/PBAT/SiO2复合材料的等温结晶动力学,研究结果表明:PLA及其共混物的Avrami指数n值分别为2.06~2.29和1.91~3.05;样品的结晶常数K(T)、半结晶时间t1/2和结晶速率τ1/2均随结晶温度的升高先增大后减小;在相同的结晶温度条件下,PLA/PBAT/SiO2样品的K(T)和t1/2均高于纯PLA的。采用改进的Avrami方程,分析PLA及PLA/PBAT/SiO2复合材料样品的非等温结晶过程。研究结果表明:PLA及其共混物的Avrami指数n1数值范围为1.31~4.88,表明晶体生长模式均为二维生长和三维生长并存;所有样品的n1均随着升温速率的增大而增大,且n1均小于n2,Zc1和Zc2也随升温速率的增大而增大。基于Mo方程分析结果与基于改进的Avrami方程分析结果一致,进一步证实了纳米SiO2的引入提高了PLA的结晶速率;且PLA/PBAT/SiO2样品的结晶活化能ΔE均大于纯PLA的,说明PBAT及SiO2的引入阻碍了PLA主链的链段向晶体生长表面的迁移过程。

    Abstract:

    The isothermal crystallization kinetics of PLA and PLA/PBAT/SiO2 composites were investigated by Avrami equation. The results showed that Avrami Indexes(n) of PLA and PLA/PBAT/SiO2 composites were 2.06~2.29 and 1.91~3.05 respectively. The crystallization constant K(T), semi-crystallization time t1/2 and crystallization rateτ1/2 were firstly increased and then decreased with the increasing crystallization temperature. The K(T) and t1/2 of PLA/PBAT/SiO2 composites were higher than those of pure PLA at the same crystallization temperature. Simultaneously, the non-isothermal crystallization kinetics of PLA and PLA/PBAT/SiO2 composites were investigated by Avrami equation with Jeziorny improvement, while n1 values were ranged from 1.31 to 4.88, indicating the coexistence of two-dimensional and three-dimensional growth in crystal growth pattern. The n1, Zc1 and Zc2 of all samples were increased with increasing heating rate, and n1 was less than n2. The result of analysis based on Mo equation was coincident with Avrami equation with Jeziorny improvement, which further indicated that the introduction of nano-SiO2 increased the crystallization rate of PLA. The crystallization activation energy ΔE of PLA/PBAT/SiO2 composites was greater than that of pure PLA, indicating that the introduction of PBAT and nano-SiO2 hindered the migration process of the segment in the main chain of the PLA to the crystal growth on the surface.

    参考文献
    相似文献
    引证文献
引用本文

周志斌,刘跃军,刘小超.改性纳米SiO2填充PLA/PBAT复合体系的 结晶动力学研究[J].包装学报,2017,9(3):9-24.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2016-09-14
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2017-09-03
  • 出版日期:
文章二维码