交联剂对HDPE/竹粉复合发泡材料性能的影响
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国家科技支撑计划基金资助项目(2014BAD02B06),广东省重大科技专项基金资助项目(2014B090921006), 湖南省自然科学杰出青年基金资助项目(13JJ1024)


Effects of Cross-Linking Agent on Properties of HDPE/Bamboo Powder Composite Foam Material
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    摘要:

    以高密度聚乙烯(HDPE)为基体塑料,偶氮二甲酰胺与氧化锌复配物为发泡剂,过氧化二异丙苯(DCP)为交联剂,采用两步模压发泡法制备了HDPE/竹粉复合发泡材料, 并研究了交联剂对复合材料密度和回弹性能、发泡性能、力学性能的影响。结果表明:当交联剂的添加质量分数为0.6%时,HDPE/竹粉复合发泡材料的密度达最小值,为0.054 g/cm3;回弹率达最大值,为90.5%;当交联剂的添加质量分数为0.4%时,复合发泡材料的泡孔分布相对多而均匀,弯曲强度达最大值,为29.3 MPa,相比未发泡材料约低8.2%,冲 击强度为6.8 kJ/m2,相比未发泡材料约低16%。

    Abstract:

    Foamed HDPE/bamboo powder composites were prepared by two step molding foaming method with HDPE as plastic matrix, Azodicarbonamide (AC) and zinc oxide (ZnO) compound as foaming agent and oxidation of Dicumyl Peroxide (DCP) as cross-linking agent. The effects of cross-linking agent on the density, rebound resilience, foaming property and mechanical property of the composites were studied. The results indicated that with the cross-linking agent content being 0.6wt%, the density of foamed HDPE/bamboo powder composites reached the minimum value of 0.054 g/cm3, and the rebound resilience ratio reached the maximum value of 90.5%. With the cross-linking agent content being 0.4wt%, the pore distribution of the foamed composite was relatively more intensive and uniform, and the bending strength reached the maximum value of 29.3 MPa, about 8.2% lower than that of non foamed composite, while the impact strength was 6.8 kJ/m2, about 16% lower than that of non foamed composite.

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胡 灿,曾广胜,黄 鹤,孙 刚.交联剂对HDPE/竹粉复合发泡材料性能的影响[J].包装学报,2017,9(2):44-49.

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  • 收稿日期:2016-08-08
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  • 在线发布日期: 2017-05-23
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