淀粉基复合发泡材料的加工流变特性及其泡孔形态
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湖南省教育厅科学研究基金资助项目(16C0459)


Processing Rheological Property and Cell Morphology of Starch-Based Composite Foaming Material
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    摘要:

    以玉米淀粉为基体,辅以相应的增塑剂和发泡剂,利用挤出发泡法制备了淀粉基复合发泡材料。运用双料筒毛细管流变仪研究了甘油增塑剂、NaHCO3发泡剂含量对淀粉基复合发泡材料流变行为的影响。采用扫描电镜(SEM)研究了不同熔体黏度对泡孔形态的影响。结果表明:淀粉基复合发泡材料的熔体流动特性表现为假塑性;随着甘油含量的增加,熔体黏度逐渐下降;随着NaHCO3含量的增加,熔体黏度先下降后提升;随着熔体黏度的降低,熔体内泡孔数量减少,孔径增大,当熔体黏度为1 200 Pa·s时,泡孔大小适中且分布均匀。

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    The starch-based composite materials were prepared by extrusion foaming method with corn starch as the main materials, plasticizer and foaming agent as the additives. The capillary rheometer was used to research the influence of glycerol plasticizer content and NaHCO3 foaming agent content on the rheological behavior of composite foaming material. Scanning electron microscopy(SEM) was also used to observe the effect of different melt viscosity on the cell morphology. The results showed that the melt flow characteristic of starch-based composite foaming material was pseudoplastic. With the increase of glycerol content, the melt viscosity decreased. With the increase of NaHCO3 content, the melt viscosity first decreased and then increased. As the melt viscosity decreased, the number of cell decreased and the pore size increased. When the melt viscosity was 1 200 Pa·s, the cell size was moderate with uniform distribution.

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孙 刚,邹思敏,梁 洁.淀粉基复合发泡材料的加工流变特性及其泡孔形态[J].包装学报,2018,10(6):50-54.

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  • 收稿日期:2018-09-10
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  • 在线发布日期: 2019-01-25
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