In order to optimize the existing recycling mode, the express package mode was proposed that the logistics department and the campus express agent cooperate in recovery operation. The optimal relationship between the price and the recovery rate of the express packaging was calculated by using Stackelberg game model with the analysis of their main influencing factors. Universities could control the recovery rate of express agents and logistics departments by changing the degree of rewards and punishments. Education, rewards and punishments could be combined to improve students’ awareness of recycling, and fully mobilize their enthusiasm, so as to protect the environment of colleges and promote the recycling of resources.