A hybrid flexible transparent electrode including graphene and PEDOT：PSS film was obtained. The graphene with few defects was prepared by modified chemical vapor deposition, and the PEDOT：PSS film was spin-coated upon the graphene to support it as a substrate. After the transfer process, the Raman spectra, optical microscope, dynamic-static contact angle meter, Atomic force microscope and four-probe transport measurements were performed to characterize the properties of the hybrid. The influence of the methane introduction, the transfer process of graphene, the amount of surfactant and the spin speed on the properties of the hybrid were analyzed. The results showed that with the flux condition, single or few layer graphene could be produced. The method by using gradient methane concentration could decrease the defect of graphene and the minimum value of ID/IG was 0.034. Surfactant could improve the morphology of hybrid electrode and the roughness of hybrid electrode was about 8 nm. With a 10 mmol/L surfactant being used, the static contact angle was 37.17°. As to the resistance of the prepared graphene, the hybrid sheet resistance was 274.8Ω/sq, with 39.77% reduction after 500 r/min PEDOT:PSS spin-coated. With the spin-coated speed of the PEDOT:PSS film higher than 1 500 r/min, the transmittance of the hybrid electrode could be greater than 90%.