背面钝化晶体太阳能电池铝浆局部背电场性能研究
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湖南省省市联合基金资助项目(2022JJ50069)


Study on the Local Back Electric Sarface Field Performance of Aluminum Pastes in Back Passivated Crystal Solar Cells
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    摘要:

    首先制备了4款不同玻璃粉添加量的背钝化铝浆样品,并在工业链式快速烧结炉上与背银和正银共烧得到背面钝化晶硅太阳能(PERC)电池片,然后采用扫描电子显微镜(SEM)、电阻测试仪以及电池片效率分选机对电池片样品进行表征,探讨了玻璃粉添加质量分数、烧结温度以及印刷单耗对局部铝掺杂背电场(L-BSF)厚度和效率的影响。结果表明:随着玻璃粉添加质量分数增加或烧结温度升高,L-BSF层厚度增大,转换效率和开路电压均先增大后降低,当玻璃粉添加质量分数为1.2%时样品的转换效率最高,达21.6%;当烧结峰值温度为780 ℃时,样品的转换效率最高,达21.4%;随着印刷单耗增大,转换效率先增加后降低,开路电压降低,L-BSF层厚度基本不变,当印刷单耗为0.18 g时,样品的转换效率最高,达21.6%。

    Abstract:

    With four kinds of back passivation aluminum paste samples prepared with different glass powder additions, back passivated crystalline silicon solar cells (PERC) can be obtained by co-firing with the back silver and the positive silver in the chain type rapid sintering furnace of the industrial production line. The scanning electron microscope (SEM), resistance tester and cell efficiency sorter are used to characterize the cell sample, followed by an inquiry into the effects of glass powder addition mass fraction, sintering temperature and printing unit consumption on the thickness and efficiency of local aluminum-doped back surface field (L-BSF). The results show that with the increase of glass powder content or sintering temperature, the thickness of L-BSF layer increases, while the conversion efficiency and open-circuit voltage shows a trend of an initial increase and a subsequent decrease. When the glass powder content is 1.2%, the sample is characterized with the highest conversion efficiency, reaching as high as 21.6%. When the sintering peak temperature is maintained at 780 ℃, the conversion efficiency of the sample is the highest, up to 21.4%; with the increase of printing unit consumption, the conversion efficiency first increases and then decreases; meanwhile, the open-circuit voltage decreases, while the thickness of L-BSF layer remains basically unchanged. When the printing unit consumption is 0.18 g, the conversion efficiency of the sample reaches up to 21.6%, the maxim of its conversion efficiency.

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周 浩,曾 凯,孟文静,刘建龙.背面钝化晶体太阳能电池铝浆局部背电场性能研究[J].湖南工业大学学报,2023,37(3):27-33.

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  • 收稿日期:2022-08-23
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  • 在线发布日期: 2023-05-10
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