无烟助镀剂热浸镀锌的镀件质量和镀层性能研究
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A Research on Casting Quality and Coating Properties of Hot-Dip Galvanizing in the Smokeless Flux
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    摘要:

    研发了一种热浸镀锌无烟助镀剂,其配方为250 g/L ZnCl2 + 20 g/L SnCl2 + 12 g/L CeCl3 +10 g/L NaCl+20 g/L KF +1g/L表面活性剂;助镀工艺中助镀温度为60 ℃,助镀时间为30 s,浸镀温度为 (450±10)℃,浸镀时间为30 s。将制备的助镀剂与传统助镀剂进行了比较,用金相显微镜和扫描电镜对助镀剂盐膜形貌进行了观察,对镀件的外观质量和镀层的厚度和结构进行了分析与研究,同时通过极化曲线和全浸试验对镀层的耐腐蚀性进行了检测。结果表明:在无烟助镀剂条件下,助镀剂的盐膜较传统助镀剂盐膜分布更均匀致密,两种助镀剂条件下镀件表面均无漏镀且平整光滑,无烟助镀剂条件下镀件镀层的厚度有所减小,镀层的合金层组织更为致密,相层受到一定程度上的抑制,镀件镀层的耐腐蚀性相较于传统助镀剂条件下的提高了25%~50%。

    Abstract:

    A smokeless flux has been developed, with 250 g/L ZnCl2 + 20 g/L SnCl2 + 12 g/L CeCl3 +10 g/L NaCl+20 g/L KF +1g/L surface active agent in the formula, with 60 ℃ the fluxing temperature, 30 s the fluxing time, (450± 10) ℃ the dip temperature, 30 s the dip plating time in the plating process. A comparison has been made between the smokeless flux and the traditional flux, and a thorough observation has been made of the flux salt film morphology under the metallographic microscope and SEM, and a research has been conducted on the casing quality and the coating thickness and structures, followed by a testing of the corrosion resistance of the coatings with the aid of polarization curves and immersion test results. The experimental results show that, compared with the traditional flux, the smokeless flux has a more homogeneous and thicker distribution of salt membrane. The casting surface is free of leakage and smooth with both fluxes, with a decreased coating thickness and a more compact alloy coating for the smokeless flux. With the phase layer suppressed to a certain extent, its coating corrosion resistance has increases by about 25%~50% compared with the traditional flux.

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徐 娟,满瑞林,秘 雪,李 波,扶 强.无烟助镀剂热浸镀锌的镀件质量和镀层性能研究[J].湖南工业大学学报,2016,30(4):53-59.

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  • 收稿日期:2016-06-15
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  • 在线发布日期: 2016-10-24
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