For the exploration of the differences simply in volleyball teaching effects between the“Internet + Education”and the traditional teaching mode, this paper accordingly applies the teaching experiments of both the modes. The results show that through the experiment, students in the experimental group and the control group reflect remarkable differences in the examination grades of the basic theoretical conception of volleyball, and the former group outperforms the latter; similarly, the overwhelm differences are found in the practical volleyball technique assessment results, featuring the higher grades of the experimental group; in the regard of learning attitude, there is one more positive impact among students majoring in sports subject to the“Internet + Education” teaching mode than those under the traditional teaching mode. Overall, the teaching effects with the“Internet+ Education”teaching mode have an advantage over that with the traditional teaching mode in the volleyball teaching of college sports major.